CAS 612-83-9 · 3,3'-Dichlorobenzidine Dihydrochloride

3,3'-Dichlorobenzidine Dihydrochloride: direct from source to Europe

3,3'-Dichlorobenzidine Dihydrochloride (CAS 612-83-9) is the dihydrochloride salt of a benzidine-type diamine, used as a diazo component for diarylide (benzidine yellow and orange) azo pigments. It is a regulated carcinogen and is supplied only for controlled industrial use under closed processes.

  • COA, SDS & TDS with every batch
  • REACH status confirmed before quote
  • Samples available for qualification
Purityup to 98%+HPLC assay, premium grade
Lead time3 – 6 weeksOrigin to European port
FormSolid25 kg bags to bulk
Response1 business dayQuotation after receiving your spec
Product identification

3,3'-Dichlorobenzidine Dihydrochloride: names, synonyms and identifiers

Buyers search for this material under several names. Whichever one appears on your specification, purchase order or REACH dossier, it is the same compound: 3,3'-Dichlorobenzidine Dihydrochloride, CAS 612-83-9.

  • Confirmed CAS number on every COA
  • Premium grade with assay 98%+ available
  • TDS and SDS supplied with every shipment
Common name
3,3'-Dichlorobenzidine Dihydrochloride
Synonyms
DCB dihydrochloride · 3,3'-Dichlorobiphenyl-4,4'-diamine dihydrochloride · o-Dianisidine analogue dihydrochloride salt
CAS number
612-83-9
Formula / MW
C12H12Cl4N2  /  326.05 g/mol
Chemical family
Benzidine-type diamine salt (Category 1B carcinogen)
HS code
2921 (amine-function compounds). Confirm the full code with your broker.

⚠ 3,3'-Dichlorobenzidine and its salts are classified as Category 1B carcinogens under CLP. Supplied strictly to verified professional industrial users with appropriate controls. Always match CAS 612-83-9 (the free base is CAS 91-94-1).

Technical data

3,3'-Dichlorobenzidine Dihydrochloride physical and chemical properties

Key parameters for process engineering, safety planning and storage design. Values are typical; always verify against the current TDS for your lot.

Appearance
Grey to light purple crystalline powder
Handle only under closed conditions per SDS
Melting point
Decomposes above 190 °C
No sharp melting point
Boiling point
Not applicable
Decomposes before boiling
Molecular weight
326.05
g/mol
Molecular formula
C12H12Cl4N2
Benzidine-type diamine dihydrochloride salt
Solubility
Soluble in water
Free base has very low water solubility
Physical form
Solid
Handle only under closed, contained conditions
Storage
Sealed, access-controlled
Dedicated, contained storage area
Quality & specification

3,3'-Dichlorobenzidine Dihydrochloride grade specifications: standard vs premium

Two grades are offered so your process chemist or quality team can pick what suits downstream requirements. COA parameters are confirmed before every shipment.

Parameter
Standard grade
Premium grade
Test method / note
HPLC assay
≥ 97.0%
≥ 98.0%
HPLC area %
Moisture
≤ 1.0%
≤ 0.5%
Karl Fischer titration
Sulfated ash
≤ 0.5%
≤ 0.2%
Gravimetric
Identity
Confirmed
Confirmed
HPLC or IR
Appearance
Grey to light purple crystalline powder
Grey to light purple crystalline powder
Visual check

All values are specification limits, not guaranteed minima. Actual COA figures for your lot are provided before dispatch. Non-standard specifications are available on enquiry.

Applications

Where 3,3'-Dichlorobenzidine Dihydrochloride is used

Typical end uses and synthesis routes for European manufacturers, toll processors and laboratories.

Diarylide pigment manufacture

Diazo component for Pigment Yellow 12/13/14/17 and Pigment Orange 34/13 type diarylide pigments, under fully enclosed process conditions.

Contained industrial synthesis

Supplied only into closed, engineered manufacturing systems with appropriate exposure controls.

Regulatory-controlled use only

Not supplied for open handling, formulation outside closed systems, or consumer-facing applications.

Custom synthesis

Available for contract synthesis strictly under a closed-system, authorised-use agreement.

Packaging & logistics

Packed to your site, documented for customs

3,3'-Dichlorobenzidine Dihydrochloride is handled as a dangerous good. Every shipment leaves with UN-approved packaging, CLP labelling and the full document set for European import.

Drums

Sealed fibre drums

UN-approved sealed fibre or steel drums with inner liners, designed for closed-system unloading.

25 kg net
Drums

Sealed steel drums

UN-approved sealed steel drums for higher-volume closed-system users.

200 kg net
Bulk

On request

Bulk or bulk-bag supply considered only for qualified closed-system sites.

On request
Document set included: Bill of lading · Commercial invoice · Packing list · Certificate of analysis (COA) · Safety data sheet (SDS) · Dangerous goods declaration (IMDG/ADR) · Certificate of origin · Other certificates on request
Common questions

3,3'-Dichlorobenzidine Dihydrochloride: frequently asked questions

Quick answers for European buyers. For anything else, email source@cheloragroup.com.

It is also sold as DCB dihydrochloride, 3,3'-Dichlorobiphenyl-4,4'-diamine dihydrochloride, o-Dianisidine analogue dihydrochloride salt. All refer to CAS 612-83-9. Confirm the CAS number with any supplier before ordering.

Price depends on grade, volume, packing, Incoterm and destination port, and moves with raw material markets. Send us your requirement and we will quote in EUR or USD with a landed-cost breakdown, usually within one business day.

3,3'-Dichlorobenzidine Dihydrochloride (CAS 612-83-9) is the dihydrochloride salt of a benzidine-type diamine, used as a diazo component for diarylide (benzidine yellow and orange) azo pigments. It is a regulated carcinogen and is supplied only for controlled industrial use under closed processes.

Standard grade offers 97.0% minimum HPLC assay. Premium grade offers 98.0% minimum with lower moisture and ash. Both grades are supplied only under the closed-system controls described above; grade does not change the regulatory status of the material.

Because 3,3'-dichlorobenzidine and its salts are Category 1B carcinogens under CLP, and are restricted or banned for open use in a number of jurisdictions, we supply this material only to verified industrial users operating closed, engineered manufacturing systems with documented exposure controls, and we confirm your REACH authorisation or exemption status, and any national restrictions, before quoting. Please provide your intended process and site controls with your enquiry.

3,3'-Dichlorobenzidine and its dihydrochloride salt are Category 1B carcinogens under CLP, are listed as a REACH Substance of Very High Concern, and are subject to authorisation and, in some jurisdictions, use bans or severe restrictions. We confirm the current status for your specific application and site before quoting, and supply only under appropriate contractual and regulatory controls.

Store sealed in a dedicated, access-controlled area under closed conditions, away from moisture, oxidisers and any process that could generate dust or aerosol. Use only within a closed engineered system with appropriate exposure controls.

It is treated as a toxic dangerous good (class and UN number per SDS; always confirm on the current SDS). We pack it in UN-approved, sealed containers designed for closed-system unloading, apply CLP labels including carcinogen hazard statements, and ship through licensed forwarders under IMDG for sea and ADR for European road, subject to any applicable export or use-authorisation controls.

Yes. Laboratory and pilot samples are supplied with a COA and SDS so your team can qualify the grade. Mention sample needs in your enquiry.

REACH status is confirmed before we quote. We advise on importer-of-record arrangements and whether the substance is registered for your use. Send your use descriptor and we will confirm.

Ready to source?

Get your 3,3'-Dichlorobenzidine Dihydrochloride quotation today

Send us the grade, volume, destination and Incoterm. You will receive a clear price, packaging options and a full document checklist, usually within one business day.

  • Samples to full containers
  • COA, SDS and DG documents included as standard
  • Quote in EUR or USD, your choice of Incoterm